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Beilstein J. Org. Chem. 2016, 12, 2189–2196, doi:10.3762/bjoc.12.209
Graphical Abstract
Scheme 1: Various chemical transformations of 7-oxabenzonorbornadiene 1.
Scheme 2: Nucleophilic ring-opening reactions of 7-oxabenzonorbornadiene 1.
Scheme 3: Preparation of cyclopropanated 8 and its proposed ring-opening mechanisms.
Scheme 4: Formation of the possible regioisomers for the ring opening of asymmetric C1-substituted cyclopropa...
Beilstein J. Org. Chem. 2016, 12, 239–244, doi:10.3762/bjoc.12.25
Scheme 1: Palladium-catalyzed ring-opening reactions of oxabenzonorbornadiene.
Scheme 2: Palladium-catalyzed ring-opening of 1 with p-iodotoluene.
Scheme 3: Potential regioisomers from the palladium-catalyzed ring-opening reaction of 2 with aryl iodides.
Scheme 4: Palladium-catalyzed ring-opening of C1 substituted oxabenzonorbornadiene.
Scheme 5: Proposed mechanism for the palladium-catalyzed ring-opening reaction of oxanorbornadiene.